Slag-Based Nanomaterial in the Removal of Hexavalent Chromium

被引:18
作者
Baalamurugan, J. [1 ]
Kumar, V. Ganesh [1 ]
Govindaraju, K. [1 ]
Prasad, B. S. Naveen [2 ]
Raja, V. K. Bupesh [3 ]
Padmapriya, R. [4 ]
机构
[1] Sathyabama Univ, Ctr Ocean Res, Nanosci Div, Madras 600119, Tamil Nadu, India
[2] Sathyabama Univ, Dept Chem Engn, Madras 600119, Tamil Nadu, India
[3] Sathyabama Univ, Dept Automobile Engn, Madras 600119, Tamil Nadu, India
[4] Sathyabama Univ, Dept Civil Engn, Madras 600119, Tamil Nadu, India
关键词
Slag-based nanomaterial; adsorption; alkali activation; core-shell formation;
D O I
10.1142/S0219581X17600134
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Slag-based nanomaterial is a by-product obtained during steel production and has wide range of components in the form of oxides. In this study, Induction Furnace (IF) steel slag-based application in adsorption of hexavalent chromium is investigated. IF slag has mixture of oxides mainly Fe2O3 and Chromium (VI) a highly toxic pollutant leads to environmental pollution and causes problem to human health mainly, carcinogenetic diseases. Slag-based nanomaterial is characterized using High Resolution Scanning Electron Microscope (HR-SEM) in which the size was around 100 nm and X-ray Fluorescence (XRF) spectroscopy. Further inductively coupled plasma mass spectroscopy and Fourier transform infrared spectroscopy were used for adsorption studies. Slag activation using NaOH (alkali activation) to the intent of surface hydroxyl (-OH) group attachment will be a cost-effective process in the removal of hexavalent chromium. Cr(VI) ions are adsorbed on the surface of alkali activated slag material. The coreshell formation of Fe(II)/Fe(III)/Cr(VI) and the adsorption are investigated in detail in the present study.
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页数:6
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