SYNTHESIS AND STRUCTURE OF CS4MO10P18O66

被引：37

作者：

HAUSHALTER, RC

LAI, FW

机构：

[1] Exxon Research and Engineering Co, United States

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1988年 / 76卷 / 01期

关键词：

Crystals--Structure - Metallic Compounds--Structure;

D O I：

10.1016/0022-4596(88)90210-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of Cs4Mo10P18O66 was determined from single crystal X-Ray diffraction data. Important features of the structure include nonintersecting, orthogonal Cs+-filled tunnels and two pairs of corner-sharing MoO6 octahedron, with Mo in the +4 oxidation state, bridged together by a P2O74- group and a P3O105- group coordinated to a Mo3+ center.

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页码：218 / 223

页数：6

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