STRUCTURE OF [SBCL(MN(CO)2(ETA-5-C5H5))(CO(CO)3(PPH3))2].C6H5CL

被引：0

作者：

FARRUGIA, LJ ^{[1
]}

NORMAN, NC ^{[1
]}

WEBSTER, PM ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192004578

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octacarbonyl-1kappa2C,2kappa3Ckappa3kappaC-chloro-4kappaCl-[1(eta5)-cyclopentadienyl]bis(triphenylphosphine)-2kappaP,3kappaP-antimonydicobaltmanganese(2Co-Sb,-Mn-Sb) chlorobenzene solvate, [Co2MnSbCl-(C5H5)(C18H15P)2(CO)8].C6H5Cl, M(r) = 1256.32, monoclinic, P2(1)/c, a = 16.632 (4), b = 16.906 (3), c = 19.332 (3) angstrom, beta = 93.15 (2)-degrees, V = 5428, Z = 4 D(x) = 1.54 g CM-3 lambda(Mo Kalpha) = 0.71069 angstrom, mu = 15.21 cm-1, F(000) = 2512, T = 298 K, R = 0.062 for 2821 unique observed reflections. The title complex contains an Sb atom in a slightly distorted tetrahedral environment, coordinated to two Co atoms [Sb-Co 2.569 (3) and 2.574 (3) angstrom], one Mn atom [Sb-Mn 2.460 (4) angstrom] and one Cl atom [Sb-Cl 2.439 (6) angstrom].

引用

页码：91 / 93

页数：3