SYNTHESES, LATTICE-CONSTANTS, MAGNETIC-PROPERTIES AND ELECTRICAL CONDUCTIVITIES OF PEROVSKITE TYPE SOLID-SOLUTIONS LA0.75EA0.25MN(1-X)ZXO3-EA=CA,SR,BA-Z=RU,TI

被引:3
|
作者
BREDTHAUER, J
JANSEN, M
机构
[1] Institut für Anorganische Chemie, 5300 Bonn
关键词
PEROVSKITES; LANTHANUM; CALCIUM; STRONTIUM; BARIUM; MANGANESE; RUTHENIUM; TITANIUM;
D O I
10.1016/0025-5408(91)90174-K
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Solid Solutions La0.75EA0.25Mn(1-x)Ti(x)O3 with O less-than-or-equal-to x less-than-or-equal-to 0.6 and La0.75EA0.25Mn(1-x)RuxO3 with O less-than-or-equal-to x less-than-or-equal-to 0.8 have been synthesized and characterized by magnetic (SQUID) and conductivity measurements (DC four-probe-technique). The purity of the samples obtained was verified by X-ray techniques and EDX-analysis. Most mixed crystals exhibit semiconductivity. Highest conductivity that is at the same time metallic in character occurs in the vicinity of La0.75Sr0.25 MnO3 and La0.75Ba0.25MnO3.
引用
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页码:931 / 936
页数:6
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