Syntheses and Physical-Chemical Properties of Phenylvinylidene Complexes with MnPt Core, Containing Diphenylphosphine Ligand at the Platinum Atom

被引：2

作者：

Chudin, Oleg S. ^{[1
]}

Verpekin, Victor V. ^{[1
]}

Kondrasenko, Alexander A. ^{[1
]}

Pavlenko, Nina, I ^{[1
]}

Rubaylo, Anatoly, I ^{[1
,2
]}

机构：

[1] FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia

[2] Siberian Fed Univ, 79 Svobodny, Krasnoyarsk 660041, Russia

来源：

JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2018年 / 11卷 / 03期

关键词：

manganese; platinum; vivylidene; heterometallic complexes; vinylidene complexes; carbonyl ligand; diphenylphosphine;

D O I：

10.17516/1998-2836-0085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthetic approach to the new heterobinuclear mu-phenylvinylidene complexes Cp(CO)(2)MnPt(mu-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)(3) (2)], containing diphenylphosphine ligand at the platinum atom, was developed. The compounds were studied by IR- and NMR-spectroscopy. Their molecular structures were proposed based on IR, NMR spectroscopic data.

引用

页码：390 / 400

页数：11

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