Syntheses and Physical-Chemical Properties of Phenylvinylidene Complexes with MnPt Core, Containing Diphenylphosphine Ligand at the Platinum Atom

被引：2

作者：

Chudin, Oleg S. ^{[1
]}

Verpekin, Victor V. ^{[1
]}

Kondrasenko, Alexander A. ^{[1
]}

Pavlenko, Nina, I ^{[1
]}

Rubaylo, Anatoly, I ^{[1
,2
]}

机构：

[1] FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia

[2] Siberian Fed Univ, 79 Svobodny, Krasnoyarsk 660041, Russia

来源：

JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2018年 / 11卷 / 03期

关键词：

manganese; platinum; vivylidene; heterometallic complexes; vinylidene complexes; carbonyl ligand; diphenylphosphine;

D O I：

10.17516/1998-2836-0085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A synthetic approach to the new heterobinuclear mu-phenylvinylidene complexes Cp(CO)(2)MnPt(mu-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)(3) (2)], containing diphenylphosphine ligand at the platinum atom, was developed. The compounds were studied by IR- and NMR-spectroscopy. Their molecular structures were proposed based on IR, NMR spectroscopic data.

引用

页码：390 / 400

页数：11

共 34 条

[1]

Able E. W., 1995, COMPREHENSIVE ORGANO, V10

[2] Metal segregation in bimetallic clusters and its possible role in synergism and bifunctional catalysis [J].

Adams, RD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 600 (1-2) :1-6

[3] Activation of hydrogen and related small molecules by the unsaturated cluster complex PtOs3(CO)7(PBu3t)(μ-PBu2t)(μ4-CHCMeCH) [J].

Adams, Richard D. ;

Boswell, Erin M. ;

Hall, Michael B. ;

Yang, Xinzheng .

ORGANOMETALLICS, 2008, 27 (19) :4938-4947

[4] Hydrogen activation by unsaturated mixed-metal cluster complexes: New directions [J].

Adams, Richard D. ;

Captain, Burjor .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :252-257

[5] Reactivity of a secondary phosphine platinum(II) complex with [Pt(norbornene)3] and PPh3.: Synthesis of new single phosphido-bridged derivatives of platinum(I) and phosphido-bridged platinum(II) hydrides [J].

Alonso, E ;

Forniés, J ;

Fortuño, C ;

Martín, A ;

Orpen, AG .

ORGANOMETALLICS, 2001, 20 (05) :850-859

[6]

Antonova AB, 2009, RUSS CHEM B+, V58, P955, DOI 10.1007/s11172-009-0122-3

[7] CHEMISTRY OF VINYLIDENE COMPLEXES .3. BINUCLEAR MANGANESE PLATINUM COMPLEXES WITH BRIDGING PHENYLVINYLIDENE LIGAND [J].

ANTONOVA, AB ;

KOVALENKO, SV ;

KORNIYETS, ED ;

PETROVSKY, PV ;

GULBIS, GR ;

JOHANSSON, AA .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 96 (01) :1-7

[8] CHEMISTRY OF VINYLIDENE COMPLEXES .5. THE LIGAND SUBSTITUTION-REACTIONS AT THE PLATINUM ATOM IN COMPLEXES CP(CO)2MNPT(MU-C=CHPH)L2 [J].

ANTONOVA, AB ;

KOVALENKO, SV ;

KORNIYETS, ED ;

PETROVSKY, PV ;

JOHANSSON, AA ;

DEYKHINA, NA .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 105 (02) :153-163

[9] Use of the Mn=C=C system in organometallic and organic synthesis [J].

Antonova, Alla B. .

COORDINATION CHEMISTRY REVIEWS, 2007, 251 (11-12) :1521-1560

[10] Chemistry of vinylidene complexes. XXI. Synthesis, spectroscopic and structural study of the RePt and MnPt μ-vinylidene complexes [J].

Antonova, Alla B. ;

Verpekin, Victor V. ;

Chudin, Oleg S. ;

Vasiliev, Alexander D. ;

Pavlenko, Nina I. ;

Sokolenko, William A. ;

Rubaylo, Anatoly I. ;

Semeikin, Oleg V. .

INORGANICA CHIMICA ACTA, 2013, 394 :328-336

← 1 2 3 4 →