STEREOCHEMISTRY OF OXIDATIVE ADDITION REACTIONS OF IRIDIUM(1) COMPLEXES

被引：117

作者：

COLLMAN, JP

SEARS, CT

机构：

[1] Venable Laboratories, Department of Chemistry, University of North Carolina, Chapel Hill

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 01期

关键词：

D O I：

10.1021/ic50059a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study has been made of the stereochemistry of the oxidative addition reactions of halogens, hydrogen halides, alkyl halides, and acetyl halides with trans-[IrCl(CO)((C6H5)2PCH3)2]. The stereochemistry of the resulting octahedral complexes has been assigned by a combination of nmr and far-infrared spectroscopy. Evidence supporting a kinetically controlled trans addition is reported. Reactions with mercuric chloride and perfluoroalkyl iodides are also described. © 1968, American Chemical Society. All rights reserved.

引用

页码：27 / &

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