INTERACTION BETWEEN AMINES AND POLY(N-PHENYLMALEIMIDES)

被引:0
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作者
PRADNY, M
LOKAJ, J
SEVCIK, S
机构
关键词
D O I
10.1135/cccc19932583
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interactions of substituted poly(N-phenylmaleimides) with low- and high-molecular-weight amines were studied. Colourless chloroform solutions of polymers, which carry electron-attracting substituents in benzene rings, turn intensively red on addition of amines in neutral or basic media depending on the nucleophilicity and accessibility of amino groups. Absorption spectra of the solutions in the visible range suggest that the formation of colour complexes consists in an interaction of free electron pairs of amines with adjacent carbonyl groups of the polyimides.
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页码:2583 / 2587
页数:5
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