AN EXPERIMENTAL-STUDY ON A BETA-CYCLODEXTRIN CARBONATE MEMBRANE REACTOR IN PNPA HYDROLYSIS

被引:7
作者
DRIOLI, E
NATOLI, M
KOTER, I
TROTTA, F
机构
[1] UNIV CALABRIA,DIPARTIMENTO INGN CHIM & MAT,I-87036 COSENZA,ITALY
[2] NICHOLAS COPERNICUS UNIV,INST CHEM,PL-87100 TORUN,POLAND
[3] UNIV TURIN,DIPARTIMENTO CHIM INORGAN FIS & MAT,I-10125 TURIN,ITALY
关键词
BETA-CYCLODEXTRIN CARBONATE; MEMBRANE REACTOR; HYDROLYSIS; PNPA;
D O I
10.1002/bit.260460504
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Flat sheet membranes made of polyetheretherketone, known as PEEK-WC, and O-octyloxycarbonyl beta-cyclodextrins were prepared by the phase inversion method. The cyclodextrins were entrapped in the polymeric membranes easily and simply in a single operation. Such functionalized membranes were tested for their catalytic activity. PNPA hydrolysis in a cyclodextrin membrane reactor was carried out as a model reaction. A significant improvement of reaction rate in comparison with the batch hydroxide ions catalyzed reaction was observed. (C) 1995 John Wiley & Sons, Inc.
引用
收藏
页码:415 / 420
页数:6
相关论文
共 22 条
[1]  
Bender M.L., Komiyama M., Properties. Structure and physical properties, Cyclodextrin chemistry, pp. 3-9, (1978)
[2]  
Drioli E., Zhang H.-C., A study of polyetheretherketone and polyarylsulphone ultra‐filtration membranes, Chimicaoggi, 11, pp. 59-63, (1989)
[3]  
Dubois M., Gilles K.A., Hamilton J.K., Rebers P.A., Smith F., Colorimetric method for determination of sugar and related substances, Anal. Chem., 28, (1956)
[4]  
Duchene D., Cyclodextrins and their industrial uses, (1987)
[5]  
Fujita K., Akihiro S., Taiji I., Hydrolysis of phenyl acetates with capped β‐cyclodextrins, Bioorg. Chem., 4, pp. 237-249, (1980)
[6]  
Fujita K., Shinoda A., Imoto T., Selectivity variation in hydrolysis of phenyl acetates by simple modifications of β‐cyclodextrin, Tetrahed. Lett., 21, pp. 1541-1544, (1980)
[7]  
Kesting R.E., Phase‐inversion membranes, Synthetic polymeric membranes. A structural perspective, pp. 237-286, (1985)
[8]  
Kitaura Y., Bender M.L., Ester hydrolysis catalyzed by modified cyclodextrins, Bioorg. Chem., 4, pp. 237-249, (1975)
[9]  
Mulder M., Basic principles of membrane technology, (1991)
[10]  
Mulder M., Preparation of synthetic membranes, Basic principles of membrane technology, pp. 54-109, (1991)