STUDY ON THE EFFECT OF THE INTERMOLECULAR FORCE TO THE CAPACITY RATIO IN HPLC BY SCALED PARTICLE THEORY

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作者
ZHANG, WB
SHI, JJ
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To study the effect of the intermolecular force to the capacity ratio in HPLC, the sealed particle theory and the two dimension lattice theory were respectively applied to study intermolecular interaction between the solvent molecules and the solute molecules in the liquid phase and on the stationary phase. We also derived a quantitative relationship between retention value and the intermolecular force, and the equation was testified by experiment.
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页码:943 / 949
页数:7
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