ISOLATION, X-RAY STRUCTURE, AND IMMOBILIZATION ON SILICA SURFACES OF 5-AMINOMETHYL-5,12-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECA-11-ENENICKEL(II) DIPERCHLORATE MONOHYDRATE

被引：3

作者：

CHUIKO, AA ^{[1
]}

KOLCHINSKII, AG ^{[1
]}

BELSKY, VK ^{[1
]}

SILCHENKO, SS ^{[1
]}

机构：

[1] KIEV INST SURFACE CHEM,PR NAUKI 31,KIEV 252028,UKRAINE

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1994年 / 33卷 / 01期

关键词：

NICKEL(II); TETRAAZAMACROCYCLE; X-RAY STRUCTURE; SILICA GEL; IMMOBILIZATION;

D O I：

10.1080/00958979408024261

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The violet ''arm on'' title complex (1) has been isolated. It crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a = 10.184 (2), b = 12.719 (2), c = 17.096 (2) angstrom, V = 2214.4 angstrom-3, Z = 4 and was refined to R(R(w)) = 0.060 (0.066) for 1693 reflections. The complex was attached to gamma-carboxypropylsilica. The ''blue-to-yellow'' conversion for bound complex is not completely reversible due to hydrogen bonding of complex species with the silica surface.

引用

页码：51 / 57

页数：7

共 9 条

[1]

ELLIS CD, 1984, INORG CHEM, V123, P1748

[2]

KADEN TA, 1984, TOP CURR CHEM, V121, P157

[3] MACROCYCLIC POLYAMINES WITH PENDENT PHENOL, CATECHOL, HYDROQUINONE, AND PYRIDINE GROUP [J].

KIMURA, E .

PURE AND APPLIED CHEMISTRY, 1986, 58 (11) :1461-1466

[4] NICKEL(II) COMPLEXES OF NOVEL MACROCYCLIC LIGANDS CONTAINING PENDANT NITRO-GROUPS [J].

KORYBUTDASZKIEWICZ, B ;

MROZINSKA, D ;

MROZINSKI, J .

JOURNAL OF COORDINATION CHEMISTRY, 1987, 15 (04) :357-365

[5] TETRAAZAMACROCYCLIC NICKEL(II) COMPLEXES CONTAINING A PENDANT AMINO GROUP [J].

KORYBUTDASZKIEWICZ, B .

JOURNAL OF COORDINATION CHEMISTRY, 1988, 19 (1-3) :101-112

[6] CRYSTAL AND MOLECULAR-STRUCTURE OF CATENA-5,7,12,14-TETRAMETHYL-5-ACI-NITROMETHYL-1,4,8,11-TETRAAZACYCLOTETRADEC-11-ENENICKEL(II) PERCHLORATE DIHYDRATE [J].

KRAJEWSKI, JW ;

GLUZINSKI, P ;

KORYBUTDASKIEWICZ, B ;

MISHNYOV, A ;

KEMME, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (01) :53-56

[7]

SILCHENKO SS, 1991, KOLLOID ZH, V53, P148

[8]

TYMERBAEV AV, 1982, ZH ANAL KHIM, V37, P1360

[9]

Yatsimirskii K. B., 1985, PHYSICOCHEMISTRY MET

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