AN APPROACH TO CALCULATION OF HIGH-ENERGY DISPLACEMENT REACTION YIELDS

被引：13

作者：

BAER, M

AMIEL, S

机构：

[1] Nuclear Chemistry Department, Soreq Nuclear Research Center, Yavne

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 24期

关键词：

D O I：

10.1021/ja01052a001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An attempt is made to calculate the reaction cross section for hot reactions of the type ZY + X → ZX + Y, where X and Y are isotopes. For this purpose, a model is assumed which permits a simple (classical) treatment of the three interacting particles. The reaction cross section σ(E) is obtained by averaging over initial conditions selected in a random manner, by the Monte Carlo method. The results are compared with those obtained by Karplus, et al., for reactions H2(D2) + T→ H(D)T + H(D) and with experiment. In all cases a good fit is obtained. © 1969, American Chemical Society. All rights reserved.

引用

页码：6547 / &

共 21 条

[1]

BAER M, 1969, ISRAEL J CHEM, V7, P341

[2]

BLAIS HC, 1962, J CHEM PHYS, V37, P2713

[3]

BLAIS HC, 1963, J CHEM PHYS, V39, P315

[4] BILLIARD-BALL COLLISIONS IN REACTIONS OF HOT HYDROGEN ATOMS - ISOTOPE EFFECT ON HYDROGEN DISPLACEMENT IN METHANE [J].