THEORETICAL-STUDY OF THE DIFFUSION OF LARGE MOLECULES IN MICRO-HETEROGENEOUS MEDIA - THE SMOLUCHOVSKI APPROACH

被引：6

作者：

PERNOT, P ^{[1
]}

PANSU, R ^{[1
]}

LEVY, B ^{[1
]}

FAURE, J ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,DEPT CHIM,LPPM,F-94235 CACHAN,FRANCE

来源：

CHEMICAL PHYSICS | 1993年 / 177卷 / 03期

关键词：

D O I：

10.1016/0301-0104(93)85042-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The possibility of extracting the initial location of probe molecules in a micelle from the dynamics of their diffusion towards the interface has been studied. Advantages and drawbacks of the simulation of this dynamics with a Smoluchovski-type equation are discussed on the example of bianthryl in a cetyl trimethyl ammonium chloride micelle. It appears that the size and shape of the domain where the extinction of the probe molecules occurs, has a critical role in this approach. Its accurate knowledge is a prerequisite to any precise determination of the initial location of the probes.

引用

页码：793 / 802

页数：10

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