INVESTIGATION OF THE MECHANISM OF THE UNIMOLECULAR AND THE ELECTRON-DONOR-CATALYZED THERMAL FRAGMENTATION OF SECONDARY PEROXY ESTERS - CHEMI-LUMINESCENCE OF 1-PHENYLETHYL PEROXYACETATE BY THE CHEMICALLY-INITIATED ELECTRON-EXCHANGE LUMINESCENCE MECHANISM

被引：47

作者：

DIXON, BG ^{[1
]}

SCHUSTER, GB ^{[1
]}

机构：

[1] UNIV ILLINOIS,ROGER ADAMS LAB,DEPT CHEM,ROGER ADAMS LAB,URBANA,IL 61801

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 11期

关键词：

D O I：

10.1021/ja00505a047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Our interest in highly exergonic thermal reactions of organic peroxides led us to the investigation of 1-phenylethyl peroxyacetate (1). Thermolysis of 1 in benzene solution gives a quantitative yield of acetic acid and acetophenone, 1 a small fraction of which is electronically excited. The reaction of 1 is catalyzed by a wide range of easily oxidized substances. © 1979, American Chemical Society. All rights reserved.

引用

页码：3116 / 3118

页数：3

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