INVESTIGATION OF THE MECHANISM OF THE UNIMOLECULAR AND THE ELECTRON-DONOR-CATALYZED THERMAL FRAGMENTATION OF SECONDARY PEROXY ESTERS - CHEMI-LUMINESCENCE OF 1-PHENYLETHYL PEROXYACETATE BY THE CHEMICALLY-INITIATED ELECTRON-EXCHANGE LUMINESCENCE MECHANISM

被引：47

作者：

DIXON, BG ^{[1
]}

SCHUSTER, GB ^{[1
]}

机构：

[1] UNIV ILLINOIS,ROGER ADAMS LAB,DEPT CHEM,ROGER ADAMS LAB,URBANA,IL 61801

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 11期

关键词：

D O I：

10.1021/ja00505a047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Our interest in highly exergonic thermal reactions of organic peroxides led us to the investigation of 1-phenylethyl peroxyacetate (1). Thermolysis of 1 in benzene solution gives a quantitative yield of acetic acid and acetophenone, 1 a small fraction of which is electronically excited. The reaction of 1 is catalyzed by a wide range of easily oxidized substances. © 1979, American Chemical Society. All rights reserved.

引用

页码：3116 / 3118

页数：3

共 18 条

[1] A SERIES OF TERTIARY BUTYL PERESTERS SHOWING CONCERTED DECOMPOSITION [J].

BARTLETT, PD ;

HIATT, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1398-1405

[2]

Benson S.W., 1976, THERMOCHEMICAL KINET, Vsecond

[3]

DELAHAY P, 1965, DOUBLE LAYER ELECTRO, pCH7

[4] BACTERIAL BIOLUMINESCENCE [J].

HASTINGS, JW ;

NEALSON, KH .

ANNUAL REVIEW OF MICROBIOLOGY, 1977, 31 :549-595

[5] CONCERTED MECHANISM AND PHASE EFFECTS IN DECOMPOSITIONS OF ALKYL PEROXY ESTERS [J].

HIATT, RR ;

GLOVER, LC ;

MOSHER, HS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1556-1562

[6] CHEMICALLY-INITIATED ELECTRON EXCHANGE LUMINESCENCE - NEW CHEMILUMINESCENT REACTION PATH FOR ORGANIC PEROXIDES [J].

KOO, J ;

SCHUSTER, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) :6107-6109

[7] CHEMILUMINESCENCE OF DIPHENOYL PEROXIDE - CHEMICALLY-INITIATED ELECTRON EXCHANGE LUMINESCENCE - NEW GENERAL MECHANISM FOR CHEMICAL PRODUCTION OF ELECTRONICALLY EXCITED-STATES [J].

KOO, JY ;

SCHUSTER, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) :4496-4503

[8] ENTROPIC CONTROL OF CHEMILUMINESCENT REACTIONS [J].

LISSI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (11) :3386-3387

[9] PERESTERS .12. T-BUTYL TRIPHENYLPERACETATE [J].

LORAND, JP ;

BARTLETT, PD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (14) :3294-&

[10] DECOMPOSITION OF ACETYL PEROXIDE IN OLEFINIC SOLVENTS . ACETYL PEROXIDE-CYCLOHEXENE REACTION [J].

MARTIN, JC ;

TAYLOR, JW ;

DREW, EH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (01) :129-&

← 1 2 →