This paper is devoted to a systematic study of the production of molecular and atomic ions and excited atoms in a microwave oxygen plasma, generated by surfatron in a quartz tube (i.d. 6 mm). The content of O2+, O+ and O is measured, using the optical emission spectroscopy, in a wide range of oxygen pressures (from 3.5 Pa to 10(2) Pa) and microwaves powers (from about 30 W to 300 W) delivered into the plasma. It is shown that the content of individual species O2+, O+ and O strongly depends on the conditions, particularly operating pressure p and the microwave power P, under which plasma is created. It means that the chemical reactivity of microwave plasma also strongly depends on p and P. It is of great importance for many practical applications, e.g. for a reproducible production of thin films with prescribed properties.