ELECTROCHEMICAL INVESTIGATIONS OF THE ENANTIOMER SELECTIVITY OF CHIRAL IONOPHORES IN LIQUID MEMBRANES

被引：55
作者：
THOMA, AP
VIVIANINAUER, A
SCHELLENBERG, KH
BEDEKOVIC, D
PRETSCH, E
PRELOG, V
SIMON, W
机构：
[1] Laboratorium Für Organische Chemie, Eidgenössischen Technischen Hochschule Zürich
来源：
HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 07期
关键词：
D O I：
10.1002/hlca.19790620726
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrochemical Investigations of the Enantiomer Selectivity of Chiral Ionophores in Liquid Membranes The enantiomer selectivity of a series of chiral neutral ionophores was investigated by electrochemical methods using ionophore‐solvent‐polymer membranes and chiral ammonium salts as substrates. The potentiometrically determined enantiomer selectivities are in good agreement with the results of electrodialytic transport studies. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim
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页码：2303 / 2316
页数：14
相关论文
共 32 条
[1]   PREPARATION OF NEUTRAL IONOPHORES FOR ALKALI AND ALKALINE-EARTH METAL CATIONS AND THEIR APPLICATION IN ION-SELECTIVE MEMBRANE ELECTRODES [J].
AMMANN, D ;
BISSIG, R ;
GUGGI, M ;
PRETSCH, E ;
SIMON, W ;
BOROWITZ, IJ ;
WEISS, L .
HELVETICA CHIMICA ACTA, 1975, 58 (06) :1535-1548
[2]   SYNTHESIS OF NEUTRAL LIPOPHILIC LIGANDS FOR MEMBRANE ELECTRODES WITH SELECTIVITY FOR ALKALINE-EARTH METAL-IONS [J].
AMMANN, D ;
PRETSCH, E ;
SIMON, W .
HELVETICA CHIMICA ACTA, 1973, 56 (05) :1780-1787
[3]  
BEDEKOVIC D, 1976, THESIS ETHZ
[4]   HOST-GUEST CHEMISTRY [J].
CRAM, DJ ;
CRAM, JM .
SCIENCE, 1974, 183 (4127) :803-809
[5]   CHIRAL RECOGNITION IN COMPLEXATION OF GUESTS BY DESIGNED HOST MOLECULES [J].
CRAM, DJ ;
HELGESON, RC ;
SOUSA, LR ;
TIMKO, JM ;
NEWCOMB, M ;
MOREAU, P ;
DEJONG, F ;
GOKEL, GW ;
HOFFMAN, DH ;
DOMEIER, LA ;
PEACOCK, SC ;
MADAN, K ;
KAPLAN, L .
PURE AND APPLIED CHEMISTRY, 1975, 43 (3-4) :327-349
[6]  
CRAM DJ, 1976, TECHNIQUES CHEM 2, V10, P815
[7]  
Evans EA, 1966, TRITIUM ITS COMPOUND
[8]  
GUGGI M, 1976, THESIS ETHZ
[9]   UBER N-GLYKOSIDE, .3. SPALTUNG VON 1-AMINO-1-PHENYL-ATHAN IN DIE OPTISCHEN ANTIPODEN [J].
HELFERICH, B ;
PORTZ, W .
CHEMISCHE BERICHTE-RECUEIL, 1953, 86 (08) :1034-1035
[10]  
HELFERICH B, 1969, ORG SYNTH, V49, P93
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