CATALYTIC CONVERSION OF ALCOHOLS .8. GALLIUM OXIDE AS A DEHYDRATION CATALYST

被引：10

作者：

DAVIS, BH ^{[1
]}

COOK, S ^{[1
]}

NAYLOR, RW ^{[1
]}

机构：

[1] POTOMAC STATE COLL,KEYSER,WV 26726

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 13期

关键词：

D O I：

10.1021/jo01327a022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Gallia is a very selective dehydration catalyst for several primary, secondary, and tertiary acyclic alcohols. The alkene distribution from 2-ols with about 50% cis-2-, 30% 1-, and 20% trans-2-alkene resembles those obtained with alumina. For 2-methylcyclohexanols, the cis isomer is converted more rapidly than the trans isomer and a cis-trans isomerization of the alcohol does not occur. The alkenes from the cis and the trans isomers suggest that an anti elimination is a major reaction pathway in the conversion of 2-methylcyclohexanol. In general, gallia closely resembles alumina as an alcohol conversion catalyst. © 1979, American Chemical Society. All rights reserved.

引用

页码：2142 / 2145

页数：4

共 15 条

[1]

BREMER H, 1967, Z CHEM, V7, P470

[2] DEHYDRATION AND DEHYDROGENATION OF 2-OCTANOL BY THORIUM OXIDE [J].