INTERFACIAL CONTACT AND BONDING IN AUTOHESION .2. INTERMOLECULAR FORCES

被引：26
作者：
ANAND, JN
BALWINSK.RZ
机构：
[1] The Dow Chemical Company Plastics Fundamental Research Laboratory, Midland, Michigan
来源：
JOURNAL OF ADHESION | 1969年 / 1卷 / JAN期
关键词：
D O I：
10.1080/00218466908077370
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The second stage of autohesion involves bond formation after contact is established by elastic, viscous, or viscoelastic deformation of the surfaces. The interfacial bonding for polystyrene is mainly through van der Waals intermolecular forces. Molecular repeat units across the interface interact to yield an attractive force. The intermolecular forces are derived from a 6–12 Lennard-Jones potential. The two unknown constants for this potential are determined from the equilibrium distance and comparison of the computed lattice energy with the cohesive energy. © 1969 Taylor & Francis Group, LLC. All rights reserved.
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页码：24 / &
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