OZONE, HYDROGEN-PEROXIDE OZONE AND UV OZONE TREATMENT OF CHROMIUM-COMPLEX AND COPPER-COMPLEX DYES - DECOLORIZATION AND METAL RELEASE

被引：29

作者：

ADAMS, CD

FUSCO, W

KANZELMEYER, T

机构：

[1] Environmental Systems Engineering, Clemson University, Clemson

来源：

OZONE-SCIENCE & ENGINEERING | 1995年 / 17卷 / 02期

关键词：

OZONE; ADVANCED OXIDATION; HYDROGEN PEROXIDE OZONE TREATMENT; UV OZONE TREATMENT; PREMETALIZED AZO DYES; METAL-COMPLEX DYES; DYE WASTE-WATER TREATMENT; DEMETALIZATION; CHROMIUM; COPPER; COLOR REMOVAL; TEXTILES; ION EXCHANGE; ACID BLACK 52 (CHROMIUM); DIRECT BLUE 80 (COPPER);

D O I：

10.1080/01919519508547543

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Metal-complex azo dyes constitute a significant fraction of the dyes used in the textile industry and exhibit properties such as superior light- and wash-fastness. While effluent color is not always regulated, the textile finishing industry often decolorizes wastewater using processes including chemical oxidation. In this study, the use of ozone, hydrogen peroxide/ozone and UV/ozone oxidant systems was examined for treatment of two common metal-complex (premetalized) dyes. Acid Black 52 (chromium) and Direct Blue 80 (copper). Oxidant dosages required for decolorization of these dyes were determined. The effect of bicarbonate alkalinity on the ozonation and the hydrogen peroxide/ozone processes also was examined. Results from analyses using high performance liquid chromatography with pose-column derivatization showed that inorganic copper was readily released during decolorization of Direct Blue 80 using ozonation or advanced oxidation. This release of inorganic copper is significant because it may affect the toxicity of a treated wastewater. The release of chromium from Acid Black 80's ligand structure was examined using ion exchange with strong base anion (SBA) and strong acid cation (SAC) exchange resins. The results indicate that oxidative decolorization did not result in appreciable Cr(III) in solution. Oxidation by ozone or hydrogen peroxide/ozone did cause chromium species to undergo anionic exchange reactions, however whether the resulting chromium was complexed with organic molecules as Cr(III) or whether it existed as an anionic Cr(VI) species (e.g., CrO4-2, HCrO4-, or Cr2O7-2) was not determined conclusively and is currently under examination.

引用

页码：149 / 162

页数：14

共 30 条

[11]

Kerzhner B.K., Kozhanov V.A., Sid'ko R.Y., Shevchenko M.A., Kinetics of Decoloring Aqueous Azo Dye Solutions with Ozone, Soviet J. Wat. Chem. and Technol, 8, pp. 57-60, (1986)

[12]

Saunders F.M., Gould J.P., Southerland C.R., The Effect of Solute Competition on Ozonolysis of Industrial Dyes, Water Res, 17, pp. 1407-1419, (1983)

[13]

Gould J.P., Groff K.A., The Kinetics of Ozonolysis of Synthetic Dyes, Ozone: Sci. Engrg, 9, pp. 153-164, (1987)

[14]

Carriere J., Jones J.P., Broadbent A.D., Decolorization of Textile Dye Solutions, Ozone: Science & Engrg, 15, pp. 189-200, (1993)

[15]

Matsui M., Shibata K., Muramatsu H., Ozone Fading of Dyes, Proc. Eleventh Ozone World Congress, 2, pp. S-7-87-S-7-90, (1993)

[16]

Matsui M., Hibino T., Shibata K., Takase Y., Ozonation of Dyes VI: Reaction of Chrysophenine G with Ozone in Water, 72, pp. 40-41, (1983)

[17]

Rakoczi F., Multistage Ozone Treatment of Dye Waste, Ozone: Sci. & Engrg, 13, pp. 11-21, (1991)

[18]

Kuo W.G., Decolorizing Dye Wastewater with Fenton's Reagent, Wat. Res, 26, pp. 881-886, (1992)

[19]

Peyton G.R., Glaze W.H., Mechanism of Photolytic Ozonation, Photochemistry of Environmental Aquatic Systems, Symposium Series 327, pp. 76-88, (1986)

[20]

Glaze W.H., Kang J.-W., Advanced Oxidation Processes for Treating Groundwater Contaminated with TCE and PCE: Laboratory Studies, J. Am. Water Works Assoc, 80, pp. 57-63, (1988)

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