CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES

被引：67
作者：
BROWN, JM
LLOYDJONES, GC
机构：
[1] Dyson Perrins Laboratory, Oxford, OX1 3QY, South Parks Road
来源：
TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 12期
关键词：
D O I：
10.1016/S0957-4166(00)82276-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cyclic secondary boranes derived from ephedrine and pseudoephedrine undergo rhodium complex-catalysed hydroboration of styrenes; both the regiochemistry and derived enantiomeric excess depend strongly on the structure of the catalyst with the ferrocenebiphosphine complex (12d) the most promising to date.
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页码：869 / 872
页数：4
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