CATALYTIC ASYMMETRIC HYDROBORATION WITH OXAZABOROLIDINES

被引：67

作者：

BROWN, JM

LLOYDJONES, GC

机构：

[1] Dyson Perrins Laboratory, Oxford, OX1 3QY, South Parks Road

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82276-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cyclic secondary boranes derived from ephedrine and pseudoephedrine undergo rhodium complex-catalysed hydroboration of styrenes; both the regiochemistry and derived enantiomeric excess depend strongly on the structure of the catalyst with the ferrocenebiphosphine complex (12d) the most promising to date.

引用

收藏

页码：869 / 872

页数：4

相关论文

共 19 条

[1]

BAKER RT, 1990, IN PRESS ORGANOMETAL, V9

[2]

BROWN JM, 1986, TETRAHEDRON LETT, V27, P4367

[3]

BROWN JM, 1989, ORG SYNTH, V68, P64

[4] SUBSTRATE-CONTROLLED DIASTEREOSELECTIVITY IN CATALYZED AND UNCATALYZED HYDROBORATIONS OF ALLYLIC AMINE DERIVATIVES [J].

BURGESS, K ;

OHLMEYER, MJ .

TETRAHEDRON LETTERS, 1989, 30 (43) :5857-5860

[5] DIASTEREOCONTROL IN RHODIUM-CATALYZED HYDROBORATION OF CHIRAL ACYCLIC ALLYLIC ALCOHOL DERIVATIVES [J].

BURGESS, K ;

OHLMEYER, MJ .

TETRAHEDRON LETTERS, 1989, 30 (04) :395-398

[6] ON CATALYZED AND UNCATALYZED HYDROBORATIONS OF CHIRAL ALLYLIC ALCOHOLS AND AMINES [J].

BURGESS, K ;

OHLMEYER, MJ .

TETRAHEDRON LETTERS, 1989, 30 (43) :5861-5864

[7] ENANTIOSELECTIVE HYDROBORATION MEDIATED BY HOMOCHIRAL RHODIUM CATALYSTS [J].

BURGESS, K ;

OHLMEYER, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (21) :5178-5179

[8] 1,1'-BIS[(ALKYL/ARYL)PHOSPHINO]FERROCENES - SYNTHESIS AND METAL-COMPLEX FORMATION - CRYSTAL-STRUCTURE OF 3 METAL-COMPLEXES OF FE(ETA-5-C5H4PPH2)2- [J].

BUTLER, IR ;

CULLEN, WR ;

KIM, TJ ;

RETTIG, SJ ;

TROTTER, J .

ORGANOMETALLICS, 1985, 4 (06) :972-980

[9] STRUCTURES OF 3 HYDROGENATION CATALYSTS [(P-P)RH(NBD)]CIO4 AND SOME COMPARATIVE RATE STUDIES WHERE (P-P)=(ETA-5-R1R2PC5H4)(ETA-5-R3R4PC5H4)FE (R1=R2=R3=R4=PH,R1=R2=PH,R3=R4=CME,R1=R3=PH,R2=R4=CME3) [J].

CULLEN, WR ;

KIM, TJ ;

EINSTEIN, FWB ;

JONES, T .

ORGANOMETALLICS, 1985, 4 (02) :346-351

[10] TRANSITION-METAL-PROMOTED REACTIONS OF BORON HYDRIDES .5. PALLADIUM-CATALYZED PENTABORANE(9)-OLEFIN COUPLING REACTIONS - A NEW, MILD SYNTHETIC ROUTE TO ALKENYLPENTABORANES [J].

DAVAN, T ;

CORCORAN, EW ;

SNEDDON, LG .

ORGANOMETALLICS, 1983, 2 (11) :1693-1694