ZEEMAN QUADRUPOLE RESONANCE IN POWDERS

被引：12

作者：

CREEL, RB

SEGEL, SL

ANDERSON, LA

机构：

[1] Institute for Atomic Research and Department of Physics, Iowa State University, Ames

[2] Department of Physics, Queen's University, Kingston, Ontario

[3] Kalamazoo College, Kalamazoo

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 11期

关键词：

D O I：

10.1063/1.1670987

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Zeeman patterns for spin 32 quadrupole interactions, for powder samples, have been determined for the special case of the perturbing rf magnetic field perpendicular to the small static magnetic field. A four line Zeeman pattern has been observed experimentally for 35Cl in NaClO3 and HgCl2 using an induction spectrometer, and a theoretical calculation using a zero linewidth quadrupole resonance has provided an adequate explanation. The resonance shapes and positions are insensitive to the asymmetry parameter in the electric field gradient. The technique is useful for the determination of magnetic shift parameters, and a value of 0.5% has been obtained for the parallel component of the paramagnetic shift of 35Cl in K2ReCl6. © 1969, American Institute of Physics. All rights reserved.

引用

页码：4908 / &

共 17 条

[1]

ABRAGAM A, 1961, PRINCIPLES NUCLEAR M, P255

[2] ELECTRIC FIELD GRADIENT ASYMMETRY IN SOLID CHLORINE [J].