ELECTRIC TRANSPORT PHENOMENA IN MIXED ELECTROLYTE-SOLUTIONS .1. GENERAL PHENOMENOLOGICAL ASPECTS

被引：11

作者：

TIMMERMANN, EO ^{[1
]}

机构：

[1] UNIV BUENOS AIRES,FAC CIENCIAS EXACTAS & NAT,DEPT QUIM INORGAN ANAL & QUIM FIS,BUENOS AIRES,ARGENTINA

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1979年 / 83卷 / 03期

关键词：

Compendex;

D O I：

10.1002/bbpc.19790830313

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electric transport phenomena in mixed electrolyte solutions (of more than two ion constituents) are analyzed from the phenomenological point of view. The expressions for the equivalent conductivity and the stoichiometric transport numbers are derived using the equivalent fractions, the total equivalent concentration and the conventional ionic conductivities of the ion constituents. Limiting values and limiting laws under several conditions are studied. General expressions for the ionic conductivities and the excess conductivity of ternary electrolyte solutions are given.

引用

页码：257 / 263

页数：7

共 28 条

[1]

Bennewitz K, 1929, PHYS Z, V30, P623

[2]

Davies C.W., 1962, ION ASS

[3] IONIC CONDUCTANCES IN AQUEOUS-SOLUTION AND AN EMPIRICAL CONDUCTANCE EQUATION [J].