STUDY OF THE MUTAROTATION OF D-GLUCOSE IN AQUEOUS-SOLUTION

被引：0

作者：

KODAD, H ^{[1
]}

MILLE, G ^{[1
]}

MOKHLISSE, R ^{[1
]}

机构：

[1] FAC SCI & TECH ST JEROME,CTR SPECT MOLEC,F-13397 MARSEILLE 20,FRANCE

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II | 1993年 / 317卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The variation of Huggins constant k' with time, when D-glucose is dissolved in water, may be due to the presence of D-glucose anomers (alpha and beta) in aqueous solution. The intensity changes seen for several IR bands for different times enabled us to distinguish between the vibrations of the two anomers alpha and beta and to follow the mutarotation kinetic of D-glucose.

引用

页码：307 / 310

页数：4

共 16 条

[1] FOURIER-TRANSFORM INFRARED-SPECTROSCOPY AS A POWERFUL TOOL FOR THE STUDY OF CARBOHYDRATES IN AQUEOUS-SOLUTIONS [J].

BACK, DM ;

MICHALSKA, DF ;

POLAVARAPU, PL .

APPLIED SPECTROSCOPY, 1984, 38 (02) :173-180

[2] FOURIER-TRANSFORM INFRARED-SPECTROSCOPY OF SUGARS .5. VIBRATIONAL ASSIGNMENTS AND ISOMERIZATION RATE CONSTANTS FROM TIME-DEPENDENT FT-IR SPECTRA OF SUGARS [J].

BACK, DM ;

POLAVARAPU, PL .

CARBOHYDRATE RESEARCH, 1987, 165 (02) :173-187

[3]

BOCEIK S, 1979, J CHEM SOC F1, V2, P262

[4] REFINEMENT OF CRYSTAL STRUCTURES OF BETA-D-GLUCOSE AND CELLOBIOSE [J].

CHU, SSC ;

JEFFREY, GA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :830-&

[5]

HOUGH L, 1977, SCI PROG, V64, P569

[6] The viscosity of dilute solutions of long-chain molecules. IV. Dependence on concentration [J].

Huggins, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :2716-2718

[7] Pyranose-furanose interconversions with reference to the mutarotations of galactose, levulose, lactulose,and turanose [J].

Isbell, HS ;

Pigman, WW .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1938, 20 (06) :773-798

[8] THE THERMODYNAMICS OF MUTAROTATION OF SOME SUGARS .2. THEORETICAL CONSIDERATIONS [J].

KABAYAMA, MA ;

PATTERSON, D .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1958, 36 (03) :563-573

[9] LASER-RAMAN SPECTRA OF D-GLUCOSE AND SUCROSE IN AQUEOUS-SOLUTION [J].

MATHLOUTHI, M ;

LUU, DV .

CARBOHYDRATE RESEARCH, 1980, 81 (02) :203-212

[10]

MEFFROYBIGET AM, 1977, CR ACAD SCI C CHIM, V284, P57

← 1 2 →