REACTION OF ETHYL VINYL SULFIDE AND DIVINYL SULFIDE WITH TRIETHYLSILANE AND TRIETHOXYSILANE

被引：0

作者：

VORONKOV, MG ^{[1
]}

VLASOVA, NN ^{[1
]}

KIRPICHENKO, SV ^{[1
]}

VOLSHAKOVA, SA ^{[1
]}

KEIKO, VV ^{[1
]}

TSETLINA, EO ^{[1
]}

AMOSOVA, SV ^{[1
]}

TROFIMOV, BA ^{[1
]}

KHVALOVSKII, V ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI,INST THEORET FDN CHEM PROC,PRAGUE,CZECHOSLOVAKIA

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 02期

关键词：

D O I：

10.1007/BF00925892

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of ethyl vinyl sulfide and divinyl sulfide with triethyl and triethoxysilane in the presence of H2PtCl6 and (Ph3P)3RhCl has been studied. The hydrosilylation of ethyl vinyl sulfide and divinyl sulfide proceeds nonselectively, giving a mixture of two isomeric adducts, the major product being the Farmer addition product. The hydrosilylation of divinyl sulfide is accompanied by secondary reactions, the main one being hydrosilaneinduced cleavage of the bond between the sulfur atom and the vinyl group. © 1979 Plenum Publishing Corporation.

引用

页码：389 / 393

页数：5

共 10 条

[1]

ANNENKOVA VZ, 1975, IZV SIB OTD AKAD NAU, P95

[2]

JOSHIDA K, 1973, J ORGANOMET CHEM, V50, P297

[3]

KOROLEVA GN, 1967, ZH OBSHCH KHIM, V37, P2768

[4] REINVESTIGATION OF PALLADIUM-CATALYZED HYDROSILYLATION OF 1,3-BUTADIENE BY TRIMETHYLSILANE [J].

LANGOVA, J ;

HETFLEJS, J .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1975, 40 (02) :432-441

[5]

PLUEDDEMANN EP, 1963, Patent No. 628951

[6]

PLUEDDEMANN EP, Patent No. 3186965

[7]

VORONKOV MG, 1975, ZH OBSHCH KHIM+, V45, P1191

[8]

VORONKOV MG, 1977, IAN SSSR KH, P2548

[9]

VORONKOV MG, 1976, IAN SSSR KH, P710

[10]

VYAZANKIN NS, 1967, ZH OBSHCH KHIM, V37, P1037

← 1 →