PHOTOCHEMICAL TRIFLUOROMETHYLATION OF 1-METHYLIMIDAZOLES AND 1-METHYLPYRROLES CONTAINING METHYLTHIO GROUPS

被引：14

作者：

NISHIDA, M ^{[1
]}

KIMOTO, H ^{[1
]}

FUJII, S ^{[1
]}

HAYAKAWA, Y ^{[1
]}

COHEN, LA ^{[1
]}

机构：

[1] NIDDKD, BIOORGAN CHEM LAB, BETHESDA, MD 20892 USA

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 07期

关键词：

D O I：

10.1246/bcsj.64.2255

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title reaction was achieved by UV (254 nm) irradiation with CF3I. The methylthio group was introduced to increase electron density and to limit available reactive sites in the rings. Following trifluoromethylation, the methylthio groups were readily removed by hydrogenolysis (Raney Ni) to give the desired trifluoromethyl heterocycles.

引用

页码：2255 / 2259

页数：5

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