DETERMINATION OF ENANTIOMERIC EXCESS IN DEUTERATED CHIRAL HYDROCARBONS BY VIBRATIONAL CIRCULAR-DICHROISM SPECTROSCOPY

被引：29

作者：

SPENCER, KM ^{[1
]}

CIANCIOSI, SJ ^{[1
]}

BALDWIN, JE ^{[1
]}

FREEDMAN, TB ^{[1
]}

NAFIE, LA ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

APPLIED SPECTROSCOPY | 1990年 / 44卷 / 02期

关键词：

D O I：

10.1366/0003702904085651

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

An improved procedure using vibrational circular dichroism spectroscopy for high-precision determinations of enantiomeric excess (ee) in chiral samples is described. Chiral trans-dideuteriocyclopropane is employed in the gas phase for percent ee measurements. This molecule is a member of the class of simple hydrocarbons made chiral by virtue of isotopic substitution for which no convenient and accurate alternative method of percent ee measurement is available. Percent ee determinations to within 1% are demonstrated for several ee values with and without contamination by the achiral cis-dideuteriocyclopropane species.

引用

页码：235 / 238

页数：4

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