ELECTROORGANIC SYNTHESIS .47. OXIDATION OF PARTIALLY PROTECTED CARBOHYDRATES AT THE NICKEL-HYDROXIDE ELECTRODE

被引：27

作者：

SCHAFER, HJ

SCHNEIDER, R

机构：

[1] Organisch-Chemisches Institut der Universität Münster, D-4400 Münster

来源：

TETRAHEDRON | 1991年 / 47卷 / 4-5期

关键词：

D O I：

10.1016/S0040-4020(01)87061-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Primary hydroxy groups in pyranoses are oxidized in excellent yields to the corresponding carboxylic acids. In furanose 3 the yield of acid is only moderate. Secondary hydroxy groups are inert, aside from lactols. The different reactivity of secondary and primary hydroxy groups allows the chemoselective oxidation of 8 and 10.

引用

页码：715 / 724

页数：10

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[2]

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