(3-Methylbenzonitrile-1 kappa N)-cis-tetrakis-(mu-N-phenylacetamidato)-1:2 kappa N-4:O;1:2 kappa O-4:N-dirhodium(II) (Rh-Rh)

被引：1
作者：
Eagle, Cassandra T. [1 ]
Quarshie, Fredricka [1 ]
Cook, Kevin M. [1 ]
机构：
[1] East Tennessee State Univ, Dept Chem, Box 70695, Johnson City, TN 37614 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536814016031
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complex molecule of the title compound, [Rh-2{N(C6H5)COCH3}(4)(NCC7H7)], has crystallographicallyimposed mirror symmetry. The four acetamide ligands bridging the dirhodium core are arranged in a 2,2-cis manner with two N atoms and two O atoms coordinating to the unique Rh-II atom cis to one another. The N-eq - Rh - Rh - O-eq torsion angles on the acetamide bridge are 0.75 (7) and 1.99 (9)degrees. The axial nitrile ligand completes the distorted octahedral coordination sphere of one Rh-II atom and shows a nonlinear coordination, with an Rh - N - C bond angle of 162.8 (5)degrees; the N - C bond length is 1.154 (7) angstrom.
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页码：M304 / +
页数：8
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