1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)-methyl]benzene

被引：1
|
作者：
Spencer, Lara C. [1 ]
Guzei, Ilia A. [1 ,2 ]
Segapelo, Tebogo V. [2 ]
Darkwa, James [2 ]
机构：
[1] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA
[2] Univ Johannesburg, Dept Chem, ZA-2006 Johannesburg, South Africa
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 14.1; mean σ(C-C) = 0.002 Å; R factor = 0.035; single-crystal X-ray study; T = 100 K; wR factor = 0.094;
D O I：
10.1107/S1600536812032801
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C38H30N4, a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmethyl) benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09 (5)degrees angle between their mean planes and exhibit a trans-like geometry in which the inplane lone pairs of electrons on the 2-N nitrogen atoms point in opposite directions.
引用
收藏
页码：02584 / +
页数：10
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