USE OF NAPHTHALENE AS A SOLVENT FOR SELECTIVE FORMATION OF THE 1/1 DIELS-ALDER ADDUCT OF C-60 WITH ANTHRACENE

被引：117

作者：

KOMATSU, K

MURATA, Y

SUGITA, N

TAKEUCHI, K

WAN, TSM

机构：

[1] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG

[2] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)61362-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A reaction of C-60 with an equimolar amount of anthracene in refluxing naphthalene gives the 1:1 Diels-Alder adduct in 67% yield based on consumed C-60: the adduct was fully characterized by IR, UV-vis, H-1 and C-13 NMR, and MS spectroscopy, and exhibited reversible reduction waves at the potential 0.11 to 0.19 V more negative and an irreversible oxidation peak at the potential 0.11 V less positive than those of C-60 itself.

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页码：8473 / 8476

页数：4

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