HYDRYL ANION REACTIONS .5. PRODUCTION OF SIH3NA SIH3K SIH3RB SIH3CS AND SNH3K . THEIR REACTION WITH CH3I

被引：31

作者：

AMBERGER, E

ROMER, R

LAYER, A

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)88694-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

SiH4 or SnH4 react in monoglyme or diglyme with Na, K, Rb, Cs and K/Na- or Na/Hg-alloys and yield quantitatively the very soluble alkalimetalhydryles SiH3Na, SiH3K, SiH3Rb, SiH3Cs and SnH3K. These alkalimetalhydryles couple with CH3I and yield CH3SiH3 or CH3SnH3, respectively. © 1968.

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页码：417 / &

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