THE KINETICS OF STRUCTURAL-CHANGES IN CU ADLAYERS ON AU(111)

被引：202
作者：
HOLZLE, MH
RETTER, U
KOLB, DM
机构：
[1] UNIV ULM,DEPT ELECTROCHEM,D-89069 ULM,GERMANY
[2] BUNDESANSTALT MAT FORSCH & PRUFUNG,D-12489 BERLIN,GERMANY
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 371卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(93)03235-H
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The kinetics of structural changes in the adlayer formed during underpotential deposition (and dissolution) of copper on Au(111) in sulphuric acid solution has been investigated by Potential-step experiments. The measured current transients can be described by a two-dimensional nucleation and growth mechanism which is accompanied by an adsorption (desorption) process; the two reactions occur at different sites on the electrode. The potential dependences of adsorption, desorption and growth rate obey the Butler-Volmer relation.
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页码：101 / 109
页数：9
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