STUDIES ON THE CHEMICAL-CONSTITUENTS OF CHLORANTHACEAE PLANTS .9. SYMMETRICAL SESQUITERPENE DIMER FROM CHLORANTHUS SERRATUS

被引：62

作者：

KAWABATA, J ^{[1
]}

FUKUSHI, E ^{[1
]}

MIZUTANI, J ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC AGR,DEPT APPL BIOSCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

PHYTOCHEMISTRY | 1993年 / 32卷 / 05期

关键词：

CHLORANTHUS-SERRATUS; CHLORANTHACEAE; ROOTS; SYMMETRICAL SESQUITERPENE DIMER; LINDENANE SKELETON;

D O I：

10.1016/S0031-9422(00)95119-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A novel dimeric sesquiterpene having a C2-symmetric structure was isolated from the roots of Chloranthus serratus. The unique cyclic structure, including a 12-membered ring, was elucidated principally by 1D- and 2D-NMR methods and the stereochemistry was disclosed through detecting NOEs between equivalent protons by C-13-coupled HMQC-NOESY.

引用

页码：1347 / 1349

页数：3

共 9 条

[1] CROUCH RC, 1990, MAGN RESON CHEM, V28, P774
[2] DISENTANGLING COUPLING AND NOE PATHWAYS INVOLVING POORLY RESOLVED PROTON SIGNALS - HMQC-TOCSY AND HMQC-NOESY
CROUCH, RC
MCFADYEN, RB
DALUGE, SM
MARTIN, GE
[J]. MAGNETIC RESONANCE IN CHEMISTRY, 1990, 28 (09) : 792 - 796
[3] STUDIES ON THE CHEMICAL-CONSTITUENTS OF CHLORANTHACEAE PLANTS .5. DISTRIBUTION OF LINDENANOLIDES IN THE CHLORANTHACEAE
KAWABATA, J
MIZUTANI, J
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1988, 52 (11): : 2965 - 2966
[4] STUDIES ON THE CHEMICAL-CONSTITUENTS OF CHLORANTHACEAE PLANTS .6. SHIZUKANOLIDE-D, SHIZUKANOLIDE-E AND SHIZUKANOLIDE-F, NOVEL LINDENANOLIDES FROM CHLORANTHUS SPP (CHLORANTHACEAE)
KAWABATA, J
MIZUTANI, J
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1989, 53 (01): : 203 - 207
[5] STUDIES ON THE CHEMICAL-CONSTITUENTS OF CHLORANTHACEAE PLANTS .8. DIMERIC SESQUITERPENOID ESTERS FROM CHLORANTHUS-SERRATUS
KAWABATA, J
MIZUTANI, J
[J]. PHYTOCHEMISTRY, 1992, 31 (04) : 1293 - 1296
[6] STUDIES ON THE CHEMICAL-CONSTITUENTS OF CHLORANTHACEAE PLANTS .7. SHIZUKAOL-A, A SESQUITERPENE DIMER FROM CHLORANTHUS-JAPONICUS
KAWABATA, J
FUKUSHI, Y
TAHARA, S
MIZUTANI, J
[J]. PHYTOCHEMISTRY, 1990, 29 (07) : 2332 - 2334
[7] STUDIES ON THE CHEMICAL-CONSTITUENTS OF CHLORANTHACEAE PLANTS .1. ISOLATION AND STRUCTURAL ELUCIDATION OF 4 SESQUITERPENES FROM CHLORANTHUS-JAPONICUS (CHLORANTHACEAE)
KAWABATA, J
TAHARA, S
MIZUTANI, J
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1981, 45 (06): : 1447 - 1453
[8] 2D C-13-COUPLED HMQC ROESY - A PROBE FOR NOES BETWEEN EQUIVALENT PROTONS
KAWABATA, J
FUKUSHI, E
MIZUTANI, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (03) : 1115 - 1117
[9] INVERSE-DETECTED 2-DIMENSIONAL NMR METHODS - APPLICATIONS IN NATURAL-PRODUCTS CHEMISTRY
MARTIN, GE
CROUCH, RC
[J]. JOURNAL OF NATURAL PRODUCTS, 1991, 54 (01): : 1 - 70

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