POLY[TRANS-BIS(3,4-ETHYLENEDIOXYTHIOPHENE)VINYLENE] - A LOW-BAND-GAP POLYMER WITH RAPID REDOX SWITCHING CAPABILITIES BETWEEN CONDUCTING TRANSMISSIVE AND INSULATING ABSORPTIVE STATES

被引：54

作者：

SOTZING, GA ^{[1
]}

REYNOLDS, JR ^{[1
]}

机构：

[1] UNIV FLORIDA,CTR MACROMOLEC SCI & ENGN,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000703

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-Bis(3,4-ethylenedioxythiophene)vinylene is synthesized and electrochemically polymerized to give poly[ trans-bis(3,4-ethylenedioxythiophene)vinylene] (PBEDOT-V) which exhibits a band gap of 1.4 eV and can be rapidly switched between insulating deep purple absorptive and highly conducting light blue transmissive states.

引用

页码：703 / 704

页数：2

共 12 条

[1] SYNTHESIS AND CHARACTERIZATION OF ALKYL-SUBSTITUTED POLY(THIOPHENE-2,5-DIYLVINYLENE)S [J].

BOLOGNESI, A ;

CATELLANI, M ;

PORZIO, W ;

SPERONI, F ;

GALARINI, R ;

MUSCO, A ;

PONTELLINI, R .

POLYMER, 1993, 34 (19) :4150-4155

[2] ELECTROCHEMICAL AND SPECTROSCOPIC CHARACTERIZATION OF POLYALKYLENEDIOXYTHIOPHENES [J].

DIETRICH, M ;

HEINZE, J ;

HEYWANG, G ;

JONAS, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 369 (1-2) :87-92

[3]

EEVERS W, 1994, POLYMER, V35, P4873

[4] LOW BAND-GAP CONJUGATED POLYMERS - POLY (THIENYLENE VINYLENE) AND POLY (SUBSTITUTED THIENYLENE VINYLENES) [J].

JEN, KY ;

HAN, CC ;

ELSENBAUMER, RL .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 186 :211-222

[5] HIGHLY-CONDUCTING, POLY(2,5-THIENYLENE VINYLENE) PREPARED VIA A SOLUBLE PRECURSOR POLYMER [J].

JEN, KY ;

MAXFIELD, M ;

SHACKLETTE, LW ;

ELSENBAUMER, RL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :309-311

[6]

JEN KY, 1988, J CHEM SOC CHEM COMM, P217

[7]

Jonas F., 1991, U.S. Patent, Patent No. [5035926, 5035926A]

[8] THE ELECTRONIC AND ELECTROCHEMICAL PROPERTIES OF POLY(ISOTHIANAPHTHENE) [J].

KOBAYASHI, M ;

COLANERI, N ;

BOYSEL, M ;

WUDL, F ;

HEEGER, AJ .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (12) :5717-5723

[9] ELECTROCHEMICAL SYNTHESIS AND OPTICAL ANALYSIS OF POLY[(2,2'-DITHIENYL)-5,5'-DIYLVINYLENE] [J].

MARTINEZ, M ;

REYNOLDS, JR ;

BASAK, S ;

BLACK, DA ;

MARYNICK, DS ;

POMERANTZ, M .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1988, 26 (04) :911-920

[10]

MRASE I, 1987, POLYM COMMUN, P277

← 1 2 →