Crystal structure of fac-tricarbonyl(cyclohexyl isocyanide-kappa C)(quinoline-2-carboxylato-kappa N-2,O)-rhenium(I)

被引：3
作者：
Triantis, Charalampos [1 ]
Shegani, Antonio [1 ]
Kiritsis, Christos [1 ]
Raptopoulou, Catherine [2 ]
Psycharis, Vassilis [2 ]
Pelecanou, Maria [3 ]
Pirmettis, Ioannis [1 ]
Papadopoulos, Minas [1 ]
机构：
[1] Natl Ctr Sci Res Demokritos, Inst Nucl & Radiol Sci & Technol Energy & Safety, Athens 15310, Greece
[2] Natl Ctr Sci Res Demokritos, Inst Nanosci & Nanotechnol, Athens 15310, Greece
[3] Natl Ctr Sci Res Demokritos, Inst Biosci & Applicat, Athens 15310, Greece
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
关键词：
crystal structure; rhenium(I) tricarbonyl complex; rhenium(I) cyclohexyl isocyanide and quinaldic acid complex; structural trans effect; Hirshfeld surface analysis;
D O I：
10.1107/S2056989016002206
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Re(C10H6NO2)(C7H11N)(CO)(3)], the Re-I atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octahedral. A lengthening of the axial Re-CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced pi-pi interactions. Weak C-H center dot center dot center dot O hydrogen-bonding interactions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [ 010] by C-H center dot center dot center dot H-C van der Waals contacts.
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页码：358 / +
页数：10
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