CHIRAL LEWIS ACID IN CATALYTIC ASYMMETRIC REACTIONS

被引：13
作者：
HAYASHI, Y
NARASAKA, K
机构：
[1] Department of Chemistry, Faculty of Science, The University of Tokyo
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1990年 / 48卷 / 04期
关键词：
D O I：
10.5059/yukigoseikyokaishi.48.280
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent development in the field of asymmetric reactions has realized various efficient procedures to prepare highly optically active compounds by employing chiral Lewis acids. In this review are summarized the development of the chiral Lewis acids and the application to asymmetric reactions such as the Diels-Alder reaction, [2 + 2] cycloaddition reaction, alkylation reaction, hydrocyanation etc. Structures of the complexs between carbonyl compounds and Lewis acids are briefly discussed. © 1990, The Society of Synthetic Organic Chemistry, Japan. All rights reserved.
引用
收藏
页码：280 / 290
页数：11
相关论文
共 74 条
[1]  
ASADA S, 1985, MAKROMOL CHEM, V186, P1755
[2]   CHIRAL INDUCTION IN THE CYCLOCONDENSATION OF ALDEHYDES WITH SILOXYDIENES [J].
BEDNARSKI, M ;
MARING, C ;
DANISHEFSKY, S .
TETRAHEDRON LETTERS, 1983, 24 (33) :3451-3454
[3]   ON THE INTERACTIVITY OF CHIRAL AUXILIARIES WITH CHIRAL CATALYSTS IN THE HETERO DIELS-ALDER REACTION - A NEW ROUTE TO L-GLYCOLIPIDS [J].
BEDNARSKI, M ;
DANISHEFSKY, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (23) :6968-6969
[4]   SYNTHESIS OF ISOPINOCAMPHEYLHALOGEN BORANES AND THEIR USE AS CHIRAL CATALYSTS FOR ASYMMETRICAL DIELS-ALDER REACTIONS [J].
BIR, G ;
KAUFMANN, D .
TETRAHEDRON LETTERS, 1987, 28 (07) :777-780
[5]  
Bredig G, 1912, BIOCHEM Z, V46, P7
[6]   CRYSTAL STRUCTURE OF(TICL4.CH3COOC2H5)2 [J].
BRUN, L .
ACTA CRYSTALLOGRAPHICA, 1966, 20 :739-&
[7]   ASYMMETRIC DIELS-ALDER REACTIONS OF CYCLOPENTADIENE WITH N-CROTONOYL AND N-ACRYLOYL-4,4-DIMETHYL-1,3-OXAZOLIDIN-2-ONE, MEDIATED BY CHIRAL LEWIS-ACIDS [J].
CHAPUIS, C ;
JURCZAK, J .
HELVETICA CHIMICA ACTA, 1987, 70 (02) :436-440
[8]   [2+2] CYCLOADDITIONS OF SILYL ENOL ETHERS AND DIMETHYL ACETYLENEDICARBOXYLATE, DIMETHYL FUMARATE, AND METHYL CROTONATE [J].
CLARK, RD ;
UNTCH, KG .
JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (02) :253-255
[9]   [2+2] CYCLOADDITION OF ETHYL PROPIOLATE AND SILYL ENOL ETHERS [J].
CLARK, RD ;
UNTCH, KG .
JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (02) :248-253
[10]   PRACTICAL ENANTIOSELECTIVE DIELS-ALDER AND ALDOL REACTIONS USING A NEW CHIRAL CONTROLLER SYSTEM [J].
COREY, EJ ;
IMWINKELRIED, R ;
PIKUL, S ;
XIANG, YB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) :5493-5495
12345678