SYNTHESIS, CHARACTERIZATION AND X-RAY STRUCTURE OF [PD(DPPP)(H2O)(TSO)] [TSO] (DPPP=1,3-BIS(DIPHENYLPHOSPHINO)PROPANE - TSO=P-CH3C6H4SO3), A CATALYTIC SPECIES IN CO-C2H4 COPOLYMERIZATION

被引：56

作者：

BENETOLLO, F

BERTANI, R

BOMBIERI, G

TONIOLO, L

机构：

[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY

[2] UNIV PADUA,IST CHIM & TECNOL INORGAN MAT AVANZATI,I-35100 PADUA,ITALY

[3] CNR,CTR STUDIO CHIM & TECNOL COMPOSTI METALLORGAN ELE,I-35131 PADUA,ITALY

[4] UNIV PADUA,IST CHIM IND,I-35131 PADUA,ITALY

[5] UNIV MILAN,IST CHIM FARMACEUT,I-20131 MILAN,ITALY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 233卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; PALLADIUM COMPLEXES; BIS(DIPHENYLPHOSPHINO)PROPANE COMPLEXES; CATALYSIS;

D O I：

10.1016/0020-1693(95)04505-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex was prepared by reacting Pd(AcO)(2) first with dppp and then with TsOH . H2O in MeOH at r.t. It is highly active in CO-C2H4 copolymerization in MeOH. It has been characterized by IR and H-1 and P-31 NMR spectroscopies. The X-ray structure consists of a packing of monomeric palladium cations and tosylate anions in the ratio 1:1. The palladium atom is in rather distorted square coordination.

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页码：5 / 9

页数：5

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