Ligand Displacement Reactions. IV. Catalysis of the Reaction between Trimethyl Phosphite and Tricarbonyl Complexes of Molybdenum and Tungsten

被引：7

作者：

Pidcock, A. ^{[1
]}

Smith, J. D. ^{[1
]}

Taylor, B. W. ^{[1
]}

机构：

[1] Univ Sussex, Sch Mol Sci, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANIC CHEMISTRY | 1970年 / 9卷 / 03期

关键词：

D O I：

10.1021/ic50085a041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between an excess of trimethyl phosphite and the complexes (arene)M(CO)(3) (M = Mo, arene = mesitylene; M = W, arene = methyl benzoate) to give fac-[(CH3O)(3)P](3)M(CO)(3) is markedly catalyzed by trimethyl phosphate, dimethyl sulfoxide, and dimethylformamide but only slightly catalyzed by isopropylamine and tetrahydrofuran. The kinetics fit the rate law: rate = k(2)[complex] [phosphite] + k(c)[complex] [catalyst]. Values of k(2) and k(c) are reported and discussed.

引用

页码：638 / 641

页数：4

共 21 条

[1] THE RELATIVE AFFINITIES OF LIGAND ATOMS FOR ACCEPTOR MOLECULES AND IONS [J].

AHRLAND, S ;

CHATT, J ;

DAVIES, NR .

QUARTERLY REVIEWS, 1958, 12 (03) :265-276

[2]

Arbusov A. E., 1950, IAN SSSR KH, V237

[3]

Canziani F., 1964, GAZZ CHIM ITAL, V94, P841

[4] TERTIARY PHOSPHINE OXIDE AND ARSINE OXIDE METAL CARBONYL COMPLEXES [J].

CHANDRASEGARAN, L ;

RODLEY, GA .

INORGANIC CHEMISTRY, 1965, 4 (09) :1360-+

[5] VIBRATIONAL SPECTRA + BONDING IN METAL CARBONYLS .3. FORCE CONSTANTS + ASSIGNMENTS OF CO STRETCHING MODES IN VARIOUS MOLECULES - EVALUATION OF CO BOND ORDERS [J].

COTTON, FA .

INORGANIC CHEMISTRY, 1964, 3 (05) :702-&

[6] RELATIVE SIGNS OF NMR COUPLING CONSTANTS IN PHOSPHINES AND PHOSPHINE COMPLEXES [J].

CULLINGWORTH, AR ;

PIDCOCK, A ;

SMITH, JD .

CHEMICAL COMMUNICATIONS, 1966, (04) :89-+

[7] KINETIC STUDIES OF GROUP 6 METAL CARBONYL COMPLEXES .2. SUBSTITUTION REACTIONS OF DIPYRIDYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN HEXACARBONYLS [J].

GRAHAM, JR ;

ANGELICI, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (24) :5590-&

[8] DONOR STRENGTHS IN 1,2-DICHLOROETHANE [J].

GUTMANN, V ;

STEINING.A ;

WYCHERA, E .

MONATSHEFTE FUR CHEMIE UND VERWANDTE TEILE ANDERER WISSENSCHAFTEN, 1966, 97 (02) :460-&

[9]

Heltsch C. W., 1962, INORG CHEM, V1, P392

[10] STEREOCHEMISTRY OF 5-CO-ORDINATED COMPOUNDS .3. SOME NEW PHOSPHINE COMPLEXES OF DIVALENT NICKEL AND COBALT [J].

JENSEN, KA ;

PEDERSEN, CT ;

NIELSEN, PH .

ACTA CHEMICA SCANDINAVICA, 1963, 17 (04) :1115-&

← 1 2 3 →