RADIATION-INDUCED COPOLYMERIZATION OF TETRAFLUOROETHYLENE WITH VINYL ETHERS

被引：9

作者：

HIKITA, T ^{[1
]}

TABATA, Y ^{[1
]}

OSHIMA, K ^{[1
]}

ISHIGURE, K ^{[1
]}

机构：

[1] UNIV TOKYO,DEPT NUCL ENGN,TOKYO,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1972年 / 10卷 / 10期

关键词：

POLYETHERS - POLYMERIZATION - Copolymerization - VINYL RESINS;

D O I：

10.1002/pol.1972.170101013

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Radiation-induced copolymerization of tetrafluoroethylene with various vinyl ethers has been studied. It was found that tetrafluoroethylene can be copolymerized with vinyl ethers to give alternating copolymers over a wide range of the initial monomer concentration in the monomer mixture. The rate of copolymerization is extremely high and has a maximum at an equimolar concentration of two monomers. The alternating structure of the copolymers was confirmed by the analysis of NMR spectra. Some thermal properties of the copolymers were measured by differential scanning calorimetry and DTA.

引用

页码：2941 / 2949

页数：9

共 14 条

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[J]. MACROMOLECULES, 1970, 3 (01) : 27 - &
[2] ISHIGURE K, TO BE PUBLISHED
[3] KERN RJ, 1963, MAKROMOLEKUL CHEM, V66, P126
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[6] COPOLYMERIZATION CHARACTERISTICS OF ETHYL VINYL ETHER AND ITS BETA-BROMO AND BETA-CARBETHOXY DERIVATIVES
PRICE, CC
SCHWAN, TC
[J]. JOURNAL OF POLYMER SCIENCE, 1955, 16 (82): : 577 - 588
[7] RAMSEY KC, 1964, J POLYM SCI B, V2, P865
[8] RADIATION-INDUCED COPOLYMERIZATION OF CHLOROTRIFLUOROETHYLENE WITH ETHYL VINYL ETHER
TABATA, Y
DUPLESSI.TA
[J]. JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1971, 9 (12): : 3425 - &
[9] RADIATION-INDUCED COPOLYMERIZATION OF TETRAFLUOROETHYLENE WITH PROPYLENE AT LOW TEMPERATURE
TABATA, Y
ISHIGURE, K
SOBUE, H
[J]. JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1964, 2 (5PA): : 2235 - &
[10] TABATA Y, 1965, MAKROMOLEKUL CHEM, V85, P91

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