EXPERIMENTAL ASPECTS OF METAL VAPOR SYNTHESIS OF ALKOXIDES AND ARYLOXIDES OF LANTHANIDES

被引：17
作者：
CARRETAS, JM
DEMATOS, AP
机构：
[1] Departamento de Quimica, ICEN, LNETI
来源：
MATERIALS CHEMISTRY AND PHYSICS | 1992年 / 31卷 / 1-2期
关键词：
D O I：
10.1016/0254-0584(92)90164-4
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The synthesis of metal alkoxides and aryloxides of lanthanides by the metal vapour technique has been investigated. The reactions of Ce, Sm, Eu and Yb with MeOH, EtOH and Pr(i)OH were studied. The compound Sm[OC6H3(Bu(t))2]3 was obtained from the reaction of samarium with 2,6-di-t-butylphenol.
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页码：123 / 125
页数：3
相关论文
共 7 条
[1]   SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEODYMIUM ISOPROPOXIDE CHLORIDE, ND6[OCH(CH3)2]17CL [J].
ANDERSEN, RA ;
TEMPLETON, DH ;
ZALKIN, A .
INORGANIC CHEMISTRY, 1978, 17 (07) :1962-1965
[2]   METAL ALKOXIDES AS PRECURSORS FOR ELECTRONIC AND CERAMIC MATERIALS [J].
BRADLEY, DC .
CHEMICAL REVIEWS, 1989, 89 (06) :1317-1322
[3]   PENTANUCLEAR OXOALKOXIDE CLUSTERS OF SCANDIUM, YTTRIUM, INDIUM AND YTTERBIUM, X-RAY CRYSTAL-STRUCTURES OF [M5(MU5-O)(MU3-OPRI)4 (MU2-OPRI)4(OPRI)5] (M = IN, YB) [J].
BRADLEY, DC ;
CHUDZYNSKA, H ;
FRIGO, DM ;
HAMMOND, ME ;
HURSTHOUSE, MB ;
MAZID, MA .
POLYHEDRON, 1990, 9 (05) :719-726
[4]   SYNTHESIS AND STRUCTURE OF THE POLYMETALLIC YTTRIUM ALKOXIDE COMPLEX Y3(MU-3-OCME3)(MU-3-CL)(MU-OCME3)3(OCME3)4(THF)2 AND RELATED COMPLEXES - LN3(MU-3-OR)(MU-3-X)(MU-OR)3 BUILDING-BLOCKS IN YTTRIUM AND LANTHANIDE ALKOXIDE CHEMISTRY [J].
EVANS, WJ ;
SOLLBERGER, MS ;
HANUSA, TP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (06) :1841-1850
[5]   SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE 1ST NEUTRAL HOMOLEPTIC LANTHANIDE METAL(III) ALKYLS - [LNR3] [LN = LA OR SM, R = CH(SIME3)2] [J].
HITCHCOCK, PB ;
LAPPERT, MF ;
SMITH, RG ;
BARTLETT, RA ;
POWER, PP .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (15) :1007-1009
[6]  
Lappert M. F., 1990, INORG SYN, V27, P164
[7]   CHEMISTRY OF YTTRIUM TRIISOPROPOXIDE REVISITED - CHARACTERIZATION AND CRYSTAL-STRUCTURE OF Y5(MU5-O)(MU3-OIPR)4(MU2-OIPR)4(OIPR)5 [J].
PONCELET, O ;
SARTAIN, WJ ;
HUBERTPFALZGRAF, LG ;
FOLTING, K ;
CAULTON, KG .
INORGANIC CHEMISTRY, 1989, 28 (02) :263-267
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