MILD AND EFFICIENT CONVERSION OF NITRILES TO AMIDES WITH BASIC UREA-HYDROGEN PEROXIDE ADDUCT

被引：38

作者：

BALICKI, R

KACZMAREK, L

机构：

[1] Institute of Organic Chemistry, Polish Academy of Sciences

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 22期

关键词：

D O I：

10.1080/00397919308011173

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The urea-hydrogen peroxide adduct, an inexpensive, stable and easily handled reagent has shown utility for mild and efficient transformation of nitriles into the corresponding aliphatic or aromatic amides. Reaction proceeds in aqueous acetone, within 0.5-2.5h, in the presence of catalytic amount of K2CO3, at room temperature.

引用

页码：3149 / 3155

页数：7

共 34 条

[1]

BALICKI R, 1992, LIEBIGS ANN CHEM, P883

[2] H2O2 UREA PHTHALIC-ANHYDRIDE SYSTEM - CONVENIENT REAGENT FOR THE MILD AND EFFICIENT PREPARATION OF SULFONES FROM ORGANIC SULFIDES [J].