FULLY REGIOSELECTIVE CATALYTIC CARBONYLATION OF ACRYLIC DERIVATIVES - SYNTHESIS OF METHYLMALONIC ACID BY IRON PENTACARBONYL CATALYZED HYDROCARBOXYLATION OF ACRYLIC-ACID

被引：17
|
作者：
BRUNET, JJ [1 ]
PASSELAIGUE, E [1 ]
机构：
[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE
来源：
ORGANOMETALLICS | 1990年 / 9卷 / 06期
关键词：
D O I：
10.1021/om00156a003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The catalytic, fully regioselective hydrocarboxylation of acrylic acid to methylmalonic acid is reported for the first time. This reaction, which involves Fe(CO)5 as catalyst precursor in the presence of Ca(OH)2 in a H2O-IPrOH mixture as solvent, is brought about at 70 °C under atmospheric carbon monoxide pressure. © 1990, American Chemical Society. All rights reserved.
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页码：1711 / 1713
页数：3
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