GLASS-CATALYZED HYDROLYSIS OF SILANE COUPLING AGENTS

被引：9
作者：
DALEY, LR
RODRIGUE.F
机构：
[1] School of Chemical Engineering, Cornell University, Ithaca, New York
来源：
POLYMER ENGINEERING AND SCIENCE | 1969年 / 9卷 / 06期
关键词：
D O I：
10.1002/pen.760090609
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Silane coupling agents containing organo‐functional and alkoxy groups are applied to glass fiber reinforcements from an acid solution commercially. It is found that finely divided soda glass suspended in a methanol‐water solution of various silanes promotes hydrolysis without the presence of an acid catalyst. When acid is present in addition to the glass, as in commercial application baths, rate of hydrolysis is lower than with either acid or glass alone. There is evidence that basic glass components catalyze hydrolysis. Further work under commercial application conditions is indicated. Copyright © 1969 Society of Plastics Engineers, Inc.
引用
收藏
页码：428 / &
相关论文
共 50 条
[21]   SILANE COUPLING AGENTS ON SILICA AND FIBER GLASS AS STUDIED BY ELECTRON-SPIN-RESONANCE [J].
MALIK, R ;
WNEK, GE .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 :5-PMSE
[22]   Fabrication of highly luminescent glass incorporating CdTe nanocrystals by using silane coupling agents [J].
Li, CL ;
Ando, M ;
Murase, N .
2ND INTERNATIONAL CONFERENCE ON SEMICONDUCTOR QUANTUM DOTS, 2003, :1250-1253
[23]   Performance improvement of glass fiber/poly(butylene terephthalate) composite by silane coupling agents [J].
Jang, JS ;
Kim, HS .
POLYMER-KOREA, 1995, 19 (05) :593-605
[24]   CATIONIC SILANE COUPLING AGENTS FOR THERMOPLASTICS [J].
PLUEDDEMANN, EP .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 1973, 2 (01) :89-106
[25]   Interaction of silane coupling agents with cellulose [J].
Abdelmouleh, M ;
Boufi, S ;
ben Salah, A ;
Belgacem, MN ;
Gandini, A .
LANGMUIR, 2002, 18 (08) :3203-3208
[26]   RAMAN STUDIES OF SILANE COUPLING AGENTS [J].
SHIH, PTK ;
KOENIG, JL .
MATERIALS SCIENCE AND ENGINEERING, 1975, 20 (02) :145-154
[27]   ADHESION THROUGH SILANE COUPLING AGENTS [J].
PLUEDDEMANN, EP .
JOURNAL OF ADHESION, 1970, 2 :184-+
[28]   Protecting metals with silane coupling agents [J].
van Ooij, WJ ;
Child, T .
CHEMTECH, 1998, 28 (02) :26-35
[29]   SILANE COUPLING AGENTS - PLUEDDEMANN,EP [J].
ROCH, KM .
CHEMISTRY IN BRITAIN, 1983, 19 (05) :421-421
[30]   SILANE COUPLING AGENTS - PLUEDDEMANN,EP [J].
BLOCK, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) :5527-5528
12345