SOLUBILITY IN WATER OF NORMAL C9 AND C10 ALKANE HYDROCARBONS

被引：112

作者：

MCAULIFFE, C

机构：

[1] Chevron Oil Field Research Company, La Habra, CA

来源：

SCIENCE | 1969年 / 163卷 / 3866期

关键词：

D O I：

10.1126/science.163.3866.478

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A new method for equilibrating water containing alkane hydrocarbons with a gas phase and analyzing the gas for hydrocarbon content by gas chromatography extends analytical sensitivity to better than 0.1 part per billion. The solubilities at 25°C of the normal C9 (220 parts per billion) and C10 (52 parts per billion) alkanes decrease with increasing carbon number. A discontinuity occurs at the normal C11 alkane, probably because of a change from true solubility (molecular dispersion) to accommodation (aggregation).

引用

页码：478 / +

页数：1

共 9 条

[1]

Baker E. G, 1967, FUNDAMENTAL ASPECTS, P299

[2] DETERMINATION OF APPARENT BINDING OF COUNTERIONS TO MICELLES BY ELECTROMOTIVE FORCE MEASUREMENTS [J].