STRUCTURE OF POLYMERS DERIVED FROM EXO-DICYCLOPENTADIENE AND ENDO-DICYCLOPENTADIENE

被引：18

作者：

CORNER, T

FOSTER, RG

HEPWORTH, P

机构：

[1] I.C.I. Ltd., Petrochemical and Polymer Laboratory, Runcorn, Cheshire, P.O. Box 11, The Heath

来源：

POLYMER | 1969年 / 10卷 / 05期

关键词：

D O I：

10.1016/0032-3861(69)90049-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymerization of exo- and endo-dicyclopentadiene with BF3.Et2O and PdCl2 (øCN)2 has been studied. All of the polymers except one are formed by 1,2-polymerization of the bicycloheptene double bonds. Polymerization of endo-dicyclopentadiene with BF3.Et2O leads to a polymer containing exo fused cyclopentene rings and it is suggested that this is a 1,3-polymer. This is the first time unequivocal evidence has been provided to support the formation of a 1,3-polymer from a bicycloheptene by cationic polymerization. © 1969.

引用

收藏

页码：393 / &

相关论文

共 11 条

[1] EXO-DICYCLOPENTADIENE [J].

BARTLETT, PD ;

GOLDSTEIN, IS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (10) :2553-2553

[2] THE CHEMISTRY OF DICYCLOPENTADIENE .2. ADDITION-REARRANGEMENT WITH ACIDS [J].

BRUSON, HA ;

RIENER, TW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1945, 67 (07) :1178-1180

[3] ADDITION OF BROMINE FLUORIDE TO NORBORNENE [J].

DEAN, FH ;

MARSHALL, DR ;

WARNHOFF, EW ;

PATTISON, FL .

CANADIAN JOURNAL OF CHEMISTRY, 1967, 45 (19) :2279-&

[4]

DEKOCK RJ, 1966, MAKROMOLEKUL CHEM, V95, P179

[5] METAL-DIOLEFIN COORDINATION COMPOUNDS [J].

DOYLE, JR ;

SLADE, PE ;

JONASSEN, HB .

INORGANIC SYNTHESES, 1960, 6 :216-219

[6] PROTON MAGNETIC RESONANCE SPECTRA OF CYCLOPENTADIENE OLIGOMERS AT 220 MC/SEC [J].

FOSTER, RG ;

MCIVOR, MC .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1969, (02) :188-&

[7]

FRY AJ, 1968, TETRAHEDRON LETT, P3345

[8] ADDITION REACTIONS OF EXO-TRIMETHYLENE-2-NORBORNENE [J].

KAPLAN, L ;

KWART, H ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (09) :2341-2347

[9]

Kennedy J. P., 1967, J MACROMOL SCI CHEM, V1, P345, DOI 10.1080/10601326708053976

[10] DEUTERIUM TRACER STUDIES ON COURSE OF ADDITION TO NORBORNENE .9. [J].

KWART, H ;

NYCE, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (13) :2601-&