ARYL-NNO-AZOXY-ALPHA-NITROALKANES

被引：6

作者：

LUKYANOV, OA

SALAMONOV, YB

BASS, AG

BOGDANOV, VS

STRELENKO, YA

KUZMIN, VS

STRUCHKOV, YT

BURTSEV, YN

机构：

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 10期

关键词：

AZOXYNITROALKANES; REGIOCHEMISTRY; PROTECTIVE GROUPS; X-RAY STRUCTURAL EXAMINATION;

D O I：

10.1007/BF00863827

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two methods of synthesis of aryl-NNO-azoxy-alpha-nitroalkanes bearing either one or two reactive hydrogen atoms alpha to the azoxy and nitro groups are described. These methods involve protection of the latter by easily removable groupings, those used being acetoxy-methyl and acetal fragments. The regiochemical nature of the diazene oxide groupings in aryl-NNO-azoxy-alpha-nitroalkanes obtained by oxidation of the appropriate diazenes has been established by heteronuclear NMR and x-ray structural examination. Some of the chemical properties of these diazene oxides have been examined.

引用

页码：1884 / 1894

页数：11

共 10 条

[1] OXIDATION OF 2,4-DINITROPHENYLHYDRAZONES BY NITROGEN-DIOXIDE [J].