AN UNUSUAL CHEMOSELECTIVITY IN COBALT(II) CHLORIDE CATALYZED CLEAVAGE OF OXIRANES WITH ANILINES - A HIGHLY REGIOSELECTIVE SYNTHESIS OF BETA-AMINO ALCOHOLS

被引：105

作者：

IQBAL, J

PANDEY, A

机构：

[1] Department of Chemistry, Indian Institute of Technology, Kanpur

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期

关键词：

D O I：

10.1016/0040-4039(90)87039-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cobalt(II) chloride catalyses the regioselective cleavage of oxiranes with anilines and p-methoxyanilineto the corresponding β -amino alcohols in excellent yields. Benzylic and aliphatic amines do not react under these conditions. © 1990.

引用

页码：575 / 576

页数：2

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