DIASTEREOSELECTIVE REACTIONS OF DELTA-SILOXYALLYLZIRCONIUM REAGENTS WITH ALDEHYDES

被引：6
作者：
CLARK, AJ
KASUJEE, I
PEACOCK, JL
机构：
[1] Department of Chemistry, University of Warwick, Coventry
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 39期
关键词：
D O I：
10.1016/0040-4039(95)01418-H
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
delta-Siloxyallylzirconium reagent (2) was produced by reaction of the TBDMS protected derivative (6) with zirconocene butene complex ''Cp(2)Zr''. Treatment of the delta-siloxyallylzirconium reagent (2) with various aldehydes provided predominantly anti-homoallylic alcohols
引用
收藏
页码：7137 / 7140
页数：4
相关论文
共 18 条
[1]   ALLYLBORANES - MOLECULAR DESIGN [J].
BUBNOV, YN .
PURE AND APPLIED CHEMISTRY, 1987, 59 (07) :895-906
[2]  
FLEMING I, 1988, TETRAHEDRON, V44, P3761
[3]  
Fleming I., 1991, COMPREHENSIVE ORGANI, P563
[4]   PREPARATION AND REGIOSELECTIVE AND DIASTEREOSELECTIVE REACTIONS OF ALLYLIC ZIRCONIUM REAGENTS FROM ALLYLIC ETHER DERIVATIVES [J].
ITO, H ;
TAGUCHI, T ;
HANZAWA, Y .
TETRAHEDRON LETTERS, 1992, 33 (10) :1295-1298
[5]   PREPARATION AND REACTIONS OF ALKOXY ALLYLIC ZIRCONIUM REAGENTS DERIVED FROM ACETALS OF ALPHA, BETA-UNSATURATED ALDEHYDES - REMARKABLE SUBSTITUENT EFFECTS ON REGIOSELECTIVITY [J].
ITO, H ;
TAGUCHI, T ;
HANZAWA, Y .
TETRAHEDRON LETTERS, 1992, 33 (51) :7873-7876
[6]  
ITO H, 1995, TETRAHEDRON, P4507
[7]  
MATTESON DS, 1986, SYNTHESIS-STUTTGART, P973
[8]   UNUSUAL ADDITION-REACTIONS OF ALKOXYMETHYL SUBSTITUTED ALLYLSTANNANES TO A CARBONYL COMPOUND - COMPLETE PRODUCT CONTROL BY THE ALKOXY GROUP REGARDLESS OF ORIGINAL REGIO-CHEMISTRY AND STEREO-CHEMISTRY [J].
NARUTA, Y ;
MARUYAMA, K .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) :1264-1265
[9]   METAL-PROMOTED CYCLIZATION .11. REACTION OF ZIRCONOCENE DICHLORIDE WITH ALKYLLITHIUMS OR ALKYL GRIGNARD-REAGENTS AS A CONVENIENT METHOD FOR GENERATING A ZIRCONOCENE EQUIVALANT AND ITS USE IN ZIRCONIUM-PROMOTED CYCLIZATION OF ALKENES, ALKYNES, DIENES, ENYNES, AND DIYNES [J].
NEGISHI, E ;
CEDERBAUM, FE ;
TAKAHASHI, T .
TETRAHEDRON LETTERS, 1986, 27 (25) :2829-2832
[10]   METAL-PROMOTED CYCLIZATION .31. STEREOSELECTIVE SYNTHESIS OF EXOCYCLIC ALKENES VIA ZIRCONIUM-PROMOTED ALKYL-DIENE COUPLING [J].
NEGISHI, E ;
MILLER, SR .
JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (26) :6014-6016
12