A NEW PERTURBATION METHOD FOR ELECTROLYTE-SOLUTIONS BASED ON MSA

被引：24
|
作者：
WU, JZ [1 ]
LU, JF [1 ]
LI, YG [1 ]
机构：
[1] TSING HUA UNIV,DEPT CHEM ENGN,BEIJING 100084,PEOPLES R CHINA
来源：
FLUID PHASE EQUILIBRIA | 1994年 / 101卷
关键词：
THEORY; STATISTICAL MECHANICS; PERTURBATION THEORY; ELECTROLYTES;
D O I：
10.1016/0378-3812(94)02506-1
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A new method to investigate the thermodynamic properties of electrolyte solutions is presented on the perturbation theory of fluids, where a mixture of neutral hard spheres and charged hard spheres is used as the reference system. The interaction forces of dispersion, induction, dipole and quadrupole are taken as perturbation potential. Explicit expressions for the Helmholtz free energy and internal energy are deduced and tested with MC data.
引用
收藏
页码：121 / 136
页数：16
相关论文
共 50 条
  • [41] Effect of non-associated electrolyte solutions on the behaviour of poly(vinyl alcohol)-based hydrogels
    Patachia, Silvia
    Valente, Artur J. M.
    Baciu, Claudia
    EUROPEAN POLYMER JOURNAL, 2007, 43 (02) : 460 - 467
  • [42] Temperature distribution measurement in asymmetric geometry using perturbation theory based on an optical method
    Jafariani, Fatemeh
    Akhlaghi, Ehsan A.
    Charsooghi, Mohammad A.
    INTERNATIONAL JOURNAL OF THERMAL SCIENCES, 2019, 135 : 187 - 191
  • [43] A fast forward method of gamma-gamma density logging based on perturbation theory
    Chen Qian
    Zhang Feng
    Liang QiXuan
    Diao ShuYuan
    Tian LiLi
    Fan JiLin
    Wang CaiZhi
    Liu YingMing
    Ti YongZhou
    CHINESE JOURNAL OF GEOPHYSICS-CHINESE EDITION, 2022, 65 (04): : 1528 - 1535
  • [44] New implementation of the configuration-based multi-reference second order perturbation theory
    Lei, Yibo
    Wang, Yubin
    Han, Huixian
    Song, Qi
    Suo, Bingbing
    Wen, Zhenyi
    JOURNAL OF CHEMICAL PHYSICS, 2012, 137 (14)
  • [45] Calculation of high-pressure solubility of gas in aqueous electrolyte solution based on non-primitive mean spherical approximation and perturbation theory
    Gao, GH
    Tan, ZQ
    Yu, YX
    FLUID PHASE EQUILIBRIA, 1999, 165 (02) : 169 - 182
  • [46] Rapid Impact-point Prediction Modeling Based on Perturbation Theory and Piecewise Prediction Control Method
    Wang Y.
    Yu J.-Y.
    Wang X.-M.
    Wang, Xiao-Ming (202xm@163.com), 1600, China Ordnance Industry Corporation (38): : 867 - 876
  • [47] Monte-Carlo Simulation of the Ionic Transport of Electrolyte Solutions at High Concentrations Based on the Pseudo-Lattice Model
    Ozaki, Hiroyuki
    Kuratani, Kentaro
    Kiyobayashi, Tetsu
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (07) : H576 - H583
  • [48] A Perturbation-theory-based Analytical Method for the Dual-mode Dielectric Resonator Measuring the Dielectric Properties
    Yuan C.-W.
    Chen M.
    Luo W.-F.
    Zhang Q.
    Binggong Xuebao/Acta Armamentarii, 2018, 39 (08): : 1607 - 1611
  • [49] Isotherm-Based Thermodynamic Model for Electrolyte and Nonelectrolyte Solutions Incorporating Long- and Short-Range Electrostatic Interactions
    Ohm, Peter B.
    Asato, Caitlin
    Wexler, Anthony S.
    Dutcher, Cari S.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (13) : 3244 - 3252
  • [50] A new equation of state for the hard-sphere chain fluids based on the thermodynamic perturbation theory and the multidensity integral equation
    Yeom, MS
    Chang, J
    Kim, H
    FLUID PHASE EQUILIBRIA, 2000, 173 (02) : 177 - 187
12345